RUS  ENG
Full version
JOURNALS // Vestnik Samarskogo Universiteta. Estestvenno-Nauchnaya Seriya // Archive

Vestnik Samarskogo Gosudarstvennogo Universiteta. Estestvenno-Nauchnaya Seriya, 2012 Issue 3/1(94), Pages 123–131 (Mi vsgu11)

Chemistry

Research of distribution of C1–C5 aliphatic monoatomic alcohols in a system “formation water–n-dodecane”

Yu. I. Arutyunova, A. O. Efremova, L. A. Onuchaka, V. S. Dudikovb

a Dept. of Physical Chemistry and Chromatography, Samara State University, Samara, 443011, Russian Federation
b LLC ``NT-Service'', Samara, 443001, Russian Federation

Abstract: The paper presents the experimental research of distribution of nine Ñ1–Ñ5 aliphatic monoatomic alcohols of normal and isomeric structure in a two-phased heterogenous system "formation water–n-dodecane using gas-chromatography method for the purpose of a choice of the most effective tracers for the characterization of filtrational streams and oil saturation when waterflooding. There were defined distribution constants $K_c$ in interval of temperatures 25–75$^\circ$Ñ on which basis appeared the conclusion that alcohols Ñ1–Ñ3 can be used as water (non-partitioning) tracers whereas alcohols Ñ4–Ñ5 approach for a role of partitioning tracers.

Keywords: monoatomic alcohols, system "formation water–$n$-dodecane", distribution constants, gas chromatography, tracers.

UDC: 544.344.015.5+543.544.3

Received: 01.11.2011
Revised: 01.11.2011



© Steklov Math. Inst. of RAS, 2025