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JOURNALS // Vestnik Samarskogo Universiteta. Estestvenno-Nauchnaya Seriya // Archive

Vestnik Samarskogo Gosudarstvennogo Universiteta. Estestvenno-Nauchnaya Seriya, 2011 Issue 5(86), Pages 136–143 (Mi vsgu88)

Chemistry

1,4-benzoquinone derivatives as inhibitors of corrosion and hydrogen absorption of steel at presence of SRB

S. A. Teryushevaa, G. S. Beloglazovb, S. M. Beloglazovc

a Dept. of Technology of Materials and Shipbuilding, Baltic State Fishing Fleet Academy, Kaliningrad, 236029, Russian Federation
b Dept. of Physics, University of Dodoma, United Republic of Tanzania, Dodoma, P.O. Box 259
c Dept. of Chemistry, Immanuel Kant Baltic Federal University, Kaliningrad, 236041, Russian Federation

Abstract: The results of study of the derivatives of 1,4-hydroquinone as inhibitors of microbiological corrosion and hydrogen absorption of mild steel in a water-salt media supporting the development of sulphate reducing bacteria (SRB) and close by its composition to the sea water containing biogenic hydrogen sulphide. Content of H$_2$S, bacterial titre in the corrosive meas well as its pH, E$_h$ and potential of steel $\varphi,$ were determined together with the quantity of hydrogen absorbed by surface layers of steel. Protective efficiency of the best studied species from corrosion reaches 65...84 %, as for their action against hydrogen absorption by steel specimen – 60...72 %. The decrease of the number of SRB cells due to the action of the derivatives of 1,4-hydroquinone was found to be 48...84 %, while the suppression degree – 29...57 % (at the concentration of 5 mMol/L).

Keywords: microbiologiñ corrosion, hydrogenation, sulphate reducing bacteria, inhibitors, organic compounds, biocides, derivatives of hydroquinone.

UDC: 543.42+620.197.3

Received: 18.01.2011
Revised: 01.04.2011



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