Abstract:
The effect of the addition of $5$ mol.% LaB$_6$ on the Weibull modulus of hot-pressed ceramics in ZrB$_2$-SiC is studied in this paper. The samples with a relative density
of $91$–$92\%$, a flexural strength of $300$–$315$ MPa, and a Vickers hardness of $14$–$15$ GPa
are obtained by hot pressing at an isothermal holding temperature of $1900^\circ$C and a pressure of $30$ MPa within $15$ minutes in an argon atmosphere. The addition of LaB$_6$ induces
an increase in the Weibull modulus of ceramics from $9.5$ up to $15.5$ when calculating using
the bending strength, and from $22.0$ up to $31.4$ when calculating using the hardness. The
values calculated using the hardness are somewhat overestimated due to the local impact
of the Vickers pyramid. An increase in the Weibull modulus with the addition of LaB$_6$
is associated with increasing homogeneity of the ceramic structure due to the formation
of a more developed system of interphase boundaries in three-component samples.