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Trofimov Boris Aleksandrovich

Publications in Math-Net.Ru

  1. One-pot assembly of functionalized (m-terphenyl-4'-yl)isoquinolines from 1-methylisoquinoline and electrophilic acylacetylenes

    Mendeleev Commun., 35:4 (2025),  457–460
  2. Extraordinary sulfur/oxygen exchange between P=S and C=O bonds during the reaction of γ-amino ynones ketones with secondary phosphine sulfides

    Mendeleev Commun., 35:2 (2025),  158–161
  3. One-pot synthesis of functionalized dihydroindolizinones from pyrrolylpropynoates and diethyl aminomalonate

    Mendeleev Commun., 35:1 (2025),  99–101
  4. One-pot synthesis of pyrrolooxazoles from pyrrolyl acetylenic ketones and natural aldehydes

    Mendeleev Commun., 35:1 (2025),  14–17
  5. Reaction of benzonitriles with acetylene in the KOBut/DMSO/THF system: self-organization of 2-aryl-3-ethynyl-4-aroyl-5-methylpyrroles and aminoacroleins

    Mendeleev Commun., 34:6 (2024),  868–870
  6. Annulation of 1-methylisoquinoline with pyrrolylacetylenic ketones: catalyst-free stereoselective synthesis of (E)-acylethenylpyrrolo[1',2':3,4]imidazo[2,1-a]isoquinolines

    Mendeleev Commun., 34:5 (2024),  691–693
  7. The reaction of acetylenes with aldazines in the NaOBut/DMSO system: a contribution to the pyrazole chemistry

    Mendeleev Commun., 34:1 (2024),  110–112
  8. Reaction of acetylenic carbanions with C=N bond: dynamics of development, synthetic divergence, environmental safety

    Usp. Khim., 93:10 (2024),  1–15
  9. The chemistry of heterocycles in the 21st century

    Usp. Khim., 93:7 (2024),  1–366
  10. Aza-Favorsky reaction with regioisomeric C- and N-linked 1,4-bis(imino)benzenes: Synthetic and reactivity dissimilarities

    Mendeleev Commun., 33:5 (2023),  642–644
  11. A facile synthesis of 2-ethynylpyrroles by ButOK-assisted room temperature deprotection of 2-(acylethynyl)pyrroles

    Mendeleev Commun., 33:4 (2023),  458–460
  12. Acetylene-driven multi-molecular assemblies of high complexity: imidazo[1,2-a]pyridines and 5-chloro-N-[2-(imidazo[1,2-a]pyridin-6-yl)vinyl]pyridin-2-amine

    Mendeleev Commun., 33:2 (2023),  164–166
  13. Diversifying the superbase-catalyzed C=N bond ethynylation: triaryl-1-pyrrolines and triaryl-1H-pyrroles from N-benzyl aldimines and arylacetylenes

    Mendeleev Commun., 33:1 (2023),  24–26
  14. Synthesis of alkyl-H-phosphinic acid alkyl esters from red phosphorus and alkyl bromides

    Mendeleev Commun., 32:6 (2022),  792–794
  15. Acyl-tetrahydroindolyl-capped 1,3-diynes in oxidative [4 + 2]-cycloaddition with benzylamine: a one-pot access to 2-acyl-6-phenyl-5-tetrahydroindolylpyridines

    Mendeleev Commun., 32:6 (2022),  729–731
  16. A straightforward access to 2-hydroxyoxazino[3,2-f ]phenanthridines from phenanthridine, oxalylacetylenes and water

    Mendeleev Commun., 32:4 (2022),  439–442
  17. A mechanistic insight into the chemoselectivity of the reaction between 3-phenyl-2-propynenitrile, secondary phosphine oxides and pyridinoids

    Mendeleev Commun., 31:5 (2021),  670–672
  18. Conjugated pyrrole/aminoenone and pyrrole/aminoacrylonitrile ensembles: new motives in heterocyclic chemistry

    Mendeleev Commun., 31:5 (2021),  573–583
  19. Chemoselective vinylation of aminophenols with acetylene catalyzed by sodium aminophenolates in aqueous DMSO

    Mendeleev Commun., 30:6 (2020),  788–790
  20. Multimolecular self-organization of acetylene and arylamines into 1-aryl-3-ethyl-4-vinylpyrroles in the KOBut/DMSO system

    Mendeleev Commun., 30:3 (2020),  315–317
  21. Superbase-promoted multi-molecular acetylene/arylamine self-organization to 1-arylpyrroles

    Mendeleev Commun., 30:1 (2020),  109–111
  22. Cyanoacetylene-driven base catalyzed synthesis of dihydropyrimidophenanthridinones from phenanthridine and water

    Mendeleev Commun., 30:1 (2020),  12–14
  23. Organophosphorus chemistry based on elemental phosphorus: advances and horizons

    Usp. Khim., 89:2 (2020),  225–249
  24. Catalyst-free addition of secondary phosphine chalcogenides to pyrazolecarbaldehydes

    Mendeleev Commun., 29:6 (2019),  683–685
  25. Acetylene based short route from 2,2,6,6-tetramethylpiperidin-4-one oxime to 2-(pyrazol-5-yl)-4,5,6,7-tetrahydropyrrolo[3,2-c]pyridines

    Mendeleev Commun., 29:6 (2019),  658–660
  26. Quantum chemical comparison of ethynylation and C-vinylation routes in superbase catalyzed reaction of acetylenes with imines

    Mendeleev Commun., 29:6 (2019),  622–624
  27. Single-stage synthesis of alkyl-H-phosphinic acids from elemental phosphorus and alkyl bromides

    Mendeleev Commun., 29:3 (2019),  328–330
  28. Copper(I) halide-promoted formation of 3-acyl-5-halopyridine moiety from NH-2-(2-acylethynyl)pyrroles and propargylamine

    Mendeleev Commun., 29:3 (2019),  252–253
  29. 1,2,5-Oxadiazolo[3,4-g]indoles via annelation of 6,7-dihydrobenzo[c][1,2,5]oxadiazol-4(5H)-one oxime with acetylene

    Mendeleev Commun., 29:1 (2019),  53–54
  30. Diastereoselective synthesis of 5-hydroxy-3-methylalkane-1,6-diones from ketones and acetylene in two atom-economic steps

    Mendeleev Commun., 29:1 (2019),  17–18
  31. Organofluorine chemistry: promising growth areas and challenges

    Usp. Khim., 88:5 (2019),  425–569
  32. Optical absorption evolution of silver nanocomposites with arabinogalactan-g-oligopyrrole copolymer matrix

    J. Sib. Fed. Univ. Math. Phys., 11:1 (2018),  60–65
  33. Solvent-free synthesis of 4-chalcogenophosphorylpyridines via $\mathrm{S_N^HAr}$ reaction of pyridines with secondary phosphine chalcogenides

    Mendeleev Commun., 28:6 (2018),  582–583
  34. Unfolding the frontalin chemistry: a facile selective hydrogenation of 7-methylidene-6,8-dioxabicyclo[3.2.1]octanes, 2:2 ensembles of ketones and acetylene

    Mendeleev Commun., 28:5 (2018),  513–514
  35. 2-Halopyridines in the triple reaction in the Pn/KOH/DMSO system to form tri(2-pyridyl)phosphine: Experimental and quantum-chemical dissimilarities

    Mendeleev Commun., 28:5 (2018),  472–474
  36. 2-(5-Arylterphenyl-4-yl)quinolines from 2-methylquinoline and 1-(het)aryl-3-phenylprop-2-yn-1-ones in just a one step: A miracle of molecular interplay

    Mendeleev Commun., 28:3 (2018),  267–269
  37. 2,4,6-Trisubstituted 3,4-dihydropyrans from acetylene and ketones: deacetylation in the KOBut/DMSO system

    Mendeleev Commun., 28:2 (2018),  145–146
  38. Dioximes of 1,6-heptanediones from acetylene and ketones: only three atom-economic steps

    Mendeleev Commun., 28:2 (2018),  143–144
  39. DBU as a scaffold for the synthesis of [1,3]oxazolo[2,3 : 2,3]pyrimido-[1,2-a]azepines: annulation with aromatic cyanopropargylic alcohols

    Mendeleev Commun., 28:2 (2018),  128–130
  40. Acetylene as driving and organizing molecule in the assembling reactions with chalcones in the NaOBut/DMSO superbase system

    Mendeleev Commun., 28:1 (2018),  47–48
  41. Phosphorus halide free synthesis of 1,2,3,4-tetrahydroisophosphinoline 2-oxides

    Mendeleev Commun., 28:1 (2018),  29–30
  42. Reaction of 1-(het)aryl-3-bromoprop-2-ynones with furans in solid metal oxides or salts: cross-coupling or cycloaddition?

    Mendeleev Commun., 28:1 (2018),  20–21
  43. Organoelement chemistry: promising growth areas and challenges

    Usp. Khim., 87:5 (2018),  393–507
  44. Structural effect in the reductive vinylation/phosphorylation of pyridines with alkyl propiolates and secondary phosphine chalcogenides: protonation vs. zwitterion generation

    Mendeleev Commun., 27:6 (2017),  553–555
  45. Multi-channel annulation of acetylene with 3-methyl-7,8-dihydrocinnolin-5(6H)-one oxime in the KOH/DMSO superbasic system

    Mendeleev Commun., 27:4 (2017),  344–345
  46. 2-Aminopyrimidines in just two steps from ketones, acetylenes and guanidine via β,γ enones

    Mendeleev Commun., 27:3 (2017),  283–284
  47. Microwave-assisted catalyst-free addition of secondary phosphines to fullerene C60

    Mendeleev Commun., 27:2 (2017),  198–200
  48. Ring-opening of pyridines and imidazoles with electron-deficient acetylenes: En route to metal-free organic synthesis

    Mendeleev Commun., 27:2 (2017),  109–115
  49. Regio- and stereoselective modification of cytosine with cyanopropargylic alcohols

    Mendeleev Commun., 27:1 (2017),  14–15
  50. Aluminium oxide-mediated cross-coupling of pyrroles with 1-bromo-2-(trifluoroacetyl)acetylene: a quantum-chemical insight

    Mendeleev Commun., 26:6 (2016),  480–482
  51. Base-catalyzed cascade dimerization of γ-aryl-β,γ-enones into acylated terphenyls

    Mendeleev Commun., 26:5 (2016),  378–379
  52. Synthesis of tris[2-(2-furyl)ethyl]phosphine its chalcogenides and Pdii complex

    Mendeleev Commun., 26:4 (2016),  314–316
  53. Insertion of 1,3-diphenylprop-2-yn-1-one into imidazo[4,5-b]pyridines in the presence of water: one-pot synthesis of pyrido[2,3-b][1,4]diazocin-9-ones

    Mendeleev Commun., 26:1 (2016),  16–18
  54. The reaction of 1,5,6-trimethylbenzimidazole with 1,3-diphenylprop-2-yn-1-one and water: en route to β-amino enones and benzodiazocinones

    Mendeleev Commun., 25:4 (2015),  254–256
  55. Unexpected N,N’-coordination of tris(2-pyridyl)-phosphine chalcogenides to PdCl2

    Mendeleev Commun., 25:3 (2015),  196–198
  56. Base-catalyzed α-vinylation of ketones with acetylenes as a key step in one-pot synthesis of pyrazolines and pyrazoles

    Mendeleev Commun., 25:2 (2015),  131–132
  57. Reaction of (het)aryl cyclohexyl ketoximes with acetylene in the two-phase KOH/DMSO/n-hexane system: en route to spirocyclic 3H-pyrroles

    Mendeleev Commun., 25:2 (2015),  129–130
  58. Domino assembly of functionalized cyclopentenols from 1,5-diphenylpentane-1,5-dione and phenylacetylene in the KOH/DMSO suspension

    Mendeleev Commun., 25:1 (2015),  17–18
  59. 2-(2-Ethynyl-1-aziranyl)-3,4-dihydro-2H-pyrrole: a one-pot assembly from isopropyl phenyl ketoxime and acetylene during the synthesis of 3H-pyrrole

    Mendeleev Commun., 24:6 (2014),  368–369
  60. Vinylation of trialkylamines with acyl- and cyanoacetylenes via C–N bond cleavage in the presence of water

    Mendeleev Commun., 24:4 (2014),  209–210
  61. 2,4-Diphenylpyrido[2,1-a]isoquinolinium nitrite from the domino reaction between isoquinoline, 1,3-diphenylprop-2-yn-1-one and nitromethane

    Mendeleev Commun., 24:3 (2014),  156–158
  62. Synthesis of 3,3-dimethyl-2-phenyl-3H-pyrrole from Isopropyl Phenyl Ketoxime and Acetylene: A Side Formation of 4,4-dimethyl-5-phenyl-1-vinyl-2-pyrrolidinone as Clue to the Reaction Mechanism

    Mendeleev Commun., 24:2 (2014),  100–101
  63. A shortcut to tris[2-(4-hydroxyphenyl)ethyl]phosphine oxide and 2-(4-hydroxyphenyl)ethylphosphinic acid via reaction of elemental phosphorus with 4-tert-butoxystyrene

    Mendeleev Commun., 24:1 (2014),  29–31
  64. Reactions of acetylenes in superbasic media. Recent advances

    Usp. Khim., 83:7 (2014),  600–619
  65. C-Ethynylpyrroles: synthesis and reactivity

    Usp. Khim., 83:6 (2014),  475–501
  66. One-pot synthesis of 3-(E)-styrylpyrroles from (E)-styrylmethyl ketoximes and acetylene

    Mendeleev Commun., 23:6 (2013),  340–341
  67. Cross-coupling between secondary phosphine selenides and primary or secondary amines: halogen-free synthesis of phosphinoselenoic amides

    Mendeleev Commun., 23:5 (2013),  253–254
  68. Superbase-catalyzed addition of ketones to propargyl and allenyl ethers in the KOH (KOBut)/DMSO system

    Mendeleev Commun., 23:4 (2013),  204–205
  69. Modification of g-Aminobutyric Acid with Acylacetylenes: Stereoselective C-Vinylation of the Primary Adducts and Transformation to Acylpyridines

    Mendeleev Commun., 22:6 (2012),  314–316
  70. Synthesis and Structural Characterization of the First Europium(III) Pyridylphosphine Complex, [Eu(N,N’,N”-2-Py3P)(NO3)3]

    Mendeleev Commun., 22:6 (2012),  294–296
  71. Regioselective Formylation of 1-(2-Oxiranylmethyl)-4,5,6,7-tetrahydroindole with DMF/(COCl)2: the Pyrrole vs. Oxirane Nucleophilicity

    Mendeleev Commun., 22:5 (2012),  265–266
  72. Tris(2-pyridyl)phosphine: a straightforward microwave-assisted synthesis from 2-bromopyridine and red phosphorus and coordination with cobalt(ii) dichloride

    Mendeleev Commun., 22:4 (2012),  187–188
  73. Consecutive Reactions of Dialkyl Ethynyl Carbinols with Acetylene in Superbase KOH/DMSO Suspension

    Mendeleev Commun., 22:3 (2012),  132–133
  74. Base-catalyzed O-vinylation of tertiary propargylic alcohols with acetylene: First examples

    Mendeleev Commun., 22:2 (2012),  62–63
  75. Stereospecific protonation of pyrrole-2-carboxaldehyde Z-oximes as a result of through-space cation stabilization with oxime hydroxyl

    Mendeleev Commun., 21:2 (2011),  103–105
  76. The reaction of 2-arylazo-1-vinylpyrroles with trifluoroacetic anhydride: unexpected formation of N-aryl-2,2,2-trifluoroacetamides and conjugated polymers

    Mendeleev Commun., 21:1 (2011),  36–37
  77. Free-radical addition of phosphine to vinyl ethers: atom-economic synthesis of tris(2-organyloxyethyl)phosphines and their derivatives

    Mendeleev Commun., 21:1 (2011),  17–18
  78. Radical addition of secondary phosphine sulfides and selenides to vinyl tellurides

    Mendeleev Commun., 20:6 (2010),  346–347
  79. Reaction of phosphine with allylbenzene in the KOH–DMSO system: regioselective synthesis of (1-phenylprop-2-yl)phosphine and bis(1-phenylprop-2-yl)phosphine

    Mendeleev Commun., 20:5 (2010),  275–276
  80. Synthesis of vinylphosphine oxides: vinyl selenides as vinylating agents

    Mendeleev Commun., 20:1 (2010),  20–21
  81. Elemental phosphorus in strongly basic media as phosphorylating reagent: a dawn of halogen-free ‘green’ organophosphorus chemistry

    Mendeleev Commun., 19:6 (2009),  295–302
  82. (Z)-1-Organyl-2-(2,4-dicyano-1,3-diphenyl-1,3-butadienyl)imidazoles from 1-substituted imidazoles with phenylcyanoacetylene

    Mendeleev Commun., 19:1 (2009),  42–44
  83. Complex of tris(Z-styryl)phosphine with PdCl2 as a new catalyst for the Sonogashira reaction

    Mendeleev Commun., 18:6 (2008),  318–319
  84. Chemo-, regio- and stereospecific non-catalytic addition of isonicotinic acid to, -acetylenic -hydroxy nitriles

    Mendeleev Commun., 18:5 (2008),  278–280
  85. Nucleophilic additon of phosphine to 1-(tert-butyl)-4-vinylbenzene: a short-cut to bulky secondary and tertiary phosphines and their chalcogenides

    Mendeleev Commun., 18:5 (2008),  260–261
  86. A new approach to densely functionalised azepines and dihydroazepines

    Mendeleev Commun., 18:3 (2008),  164–166
  87. Peroxidase-catalysed synthesis of electroconductive polypyrrole

    Mendeleev Commun., 18:1 (2008),  56–58
  88. Nucleophilic addition of secondary phosphine chalcogenides to, α,β-acetylenic γ-hydroxy acid nitriles and a rearrangement of the adducts

    Mendeleev Commun., 17:6 (2007),  325–326
  89. A peculiar selective rearrangement during the NiS-catalysed dehydrogenation of 4,5-dihydro-1H-benz[g]indole

    Mendeleev Commun., 17:5 (2007),  296–298
  90. A peculiar vinylation of 1-substituted imidazoles with, α,β-acetylenic γ-hydroxyacid nitriles

    Mendeleev Commun., 17:4 (2007),  237–238
  91. Free-radical addition of phosphine sulfides to aryl and hetaryl acetylenes: unprecedented stereoselectivity

    Mendeleev Commun., 17:3 (2007),  181–182
  92. Nonlinear-optical bis(3-hydroxy-2-methyl-4H-pyran-4-onato) complexes of metals

    Mendeleev Commun., 17:3 (2007),  154–155
  93. Unexpected formation of 4-methyl-1-vinyl-δ-carboline in the reaction of 3-acetylindole oxime with acetylene

    Mendeleev Commun., 17:1 (2007),  40–42
  94. Acetylene: new prospects of classical reactions

    Usp. Khim., 76:6 (2007),  550–570
  95. Transformations of cyanoacetylenic alcohols in the presence of the cyanide ion

    Mendeleev Commun., 16:4 (2006),  228–230
  96. Thiol elimination from tris[2-(phenylthio)ethyl]phosphine oxide: a convenient route to trivinylphosphine oxide

    Mendeleev Commun., 16:1 (2006),  31
  97. Superbase-catalysed addition of methanol to propyne and allene: an expedient synthesis of 2-methoxypropene

    Mendeleev Commun., 16:1 (2006),  13–14
  98. Enediyne antibiotics and their models: new potential of acetylene chemistry

    Usp. Khim., 75:9 (2006),  913–935
  99. Oximes as reagents

    Usp. Khim., 75:9 (2006),  884–912
  100. 2-(2-Benzoylethynyl)-5-phenylpyrrole: fixation of cis- and trans-rotamers in a crystal state

    Mendeleev Commun., 15:6 (2005),  229–232
  101. Unexpected double α,β-addition of secondary phosphine chalcogenides to 3-phenyl-2-propynenitrile

    Mendeleev Commun., 15:5 (2005),  183–184
  102. Reaction of anabasine with 3-(1-hydroxycyclohexyl)-2-propynenitrile: a new route to functionalised anabasine alkaloids

    Mendeleev Commun., 15:1 (2005),  33–35
  103. Atom-economic synthesis of tertiary 2-alkoxyethylphosphine sulfides

    Mendeleev Commun., 14:5 (2004),  216–217
  104. Catalytic methoxycarbonylation of alkoxyallenes

    Mendeleev Commun., 14:2 (2004),  61–63
  105. Cascade cyclization of quinoline and quinoxaline with nitriles of α,β-acetylenic γ-hydroxy acids

    Mendeleev Commun., 13:4 (2003),  186–188
  106. Synthesis of C-vinylpyrroles

    Usp. Khim., 71:7 (2002),  641–671
  107. Reactions of alkali metal acetylides with red phosphorus

    Mendeleev Commun., 10:2 (2000),  66–67
  108. An unusually fast nucleophilic addition of amidoximes to acetylene

    Mendeleev Commun., 10:1 (2000),  29–30
  109. Diacetylene: a candidate for industrially important reactions

    Usp. Khim., 69:7 (2000),  642–660
  110. Trifluoroacetylation of O-vinyl acetoxime

    Mendeleev Commun., 9:6 (1999),  238–239
  111. Addition of secondary phosphines to phenylcyanoacetylene as a route to functional phosphines

    Mendeleev Commun., 9:4 (1999),  163–164
  112. Bipyrroles, furyl- and thienylpyrroles

    Usp. Khim., 68:6 (1999),  506–531
  113. Phosphine in the synthesis of organophosphorus compounds

    Usp. Khim., 68:3 (1999),  240–253
  114. Reaction of thioacetic acid with ethenyl- and ethynyl chlorides

    Mendeleev Commun., 8:5 (1998),  185–186
  115. An example of the facile C-vinylation of pyrroles

    Mendeleev Commun., 8:3 (1998),  119–120
  116. Deprotonation of benzyl isothiocyanate: a simple route to silylated benzyl isothiocyanates

    Mendeleev Commun., 7:6 (1997),  232–233
  117. An efficient synthesis of 2-trimethylsilyloxy-4-neopentyl quinoline via 3-lithio-1-tert-butylallene and phenyl isocyanate

    Mendeleev Commun., 7:3 (1997),  92
  118. Spatial and electronic structure of vinyl and allenyl chalcogenides

    Usp. Khim., 65:12 (1996),  1091–1123
  119. Elemental phosphorus–strong base as a system for the synthesis of organophosphorus compounds

    Usp. Khim., 60:12 (1991),  2619–2632
  120. Prospects for the chemistry of pyrrole

    Usp. Khim., 58:10 (1989),  1703–1720
  121. Synthesis of pyrroles from aliphatic compounds

    Usp. Khim., 58:2 (1989),  275–302
  122. Polymerisation of N-Vinylpyrroles

    Usp. Khim., 54:6 (1985),  1034–1050
  123. Reactions of Acetylene in Superbasic Media

    Usp. Khim., 50:2 (1981),  248–272
  124. The Cleavage of the Carbon–Oxygen Bond by Organomagnesium Compounds

    Usp. Khim., 44:1 (1975),  75–103
  125. Synthesis of Vinyl Ethers Containing Functional Groups and Heteroatoms

    Usp. Khim., 37:11 (1968),  2070–2093
  126. The kinetic isotopic effect of deuterium in the hydrolysis of vinyl ethers

    Dokl. Akad. Nauk SSSR, 163:6 (1965),  1412–1415


© Steklov Math. Inst. of RAS, 2025