I. V. Nazarov, E. V. Bermesheva, K. V. Potapov, Z. B. Khesina, M. M. Ilyin, E. K. Melnikova, M. V. Bermeshev, “Palladium complex with tetrahydronaphthyl-substituted diimine ligand as a catalyst for polymerization of norbornenes and diazoacetates”, Mendeleev Commun., 31:5 (2021), 690

Эта публикация цитируется в 4 статьях

Communications

Palladium complex with tetrahydronaphthyl-substituted diimine ligand as a catalyst for polymerization of norbornenes and diazoacetates

I. V. Nazarov^a, E. V. Bermesheva^ab, K. V. Potapov^c, Z. B. Khesina^d, M. M. Ilyin^e, E. K. Melnikova^ef, M. V. Bermeshev^a

^a A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russian Federation
^b I.M. Sechenov First Moscow State Medical University, Moscow, Russian Federation
^c N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^d A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, Russian Federation
^e A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
^f Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Аннотация: New methylpalladium chloride complex with bulky N,N'-bis(1,2,3,4-tetrahydro-1-naphthyl)-substituted glyoxal diimine ligand was obtained. This complex was found to be an efficient catalyst for vinyl-addition polymerization of norbornene derivative and for polymerization of a diazoacetate, giving polycarbenes with side polar functionalities.

Ключевые слова: diimine ligands, palladium complexes, norbornenes, diazoacetates, vinyl-addition polymerization, polycarbenes.

Язык публикации: английский

DOI: 10.1016/j.mencom.2021.09.032

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