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ЖУРНАЛЫ // Mendeleev Communications // Архив

Mendeleev Commun., 2021, том 31, выпуск 5, страницы 696–697 (Mi mendc1026)

Communications

Lead tetraacetate assisted formation of bis(acetoxy)acetic acid derivative from carvone

G. R. Sunagatullina, A. N. Lobov, M. S. Miftakhov

Ufa Institute of Chemistry, Ufa Federal Research Centre of the Russian Academy of Sciences, Ufa, Russian Federation


Аннотация: R-Carvone on heating with Pb(OAc)4 in benzene gives (2RS)-2-hydroxy-2-[(1S)-4-methyl-5-oxocyclohex-3-en-1-yl)]-prop-1-yl bis(acetoxy)acetate. Alkaline hydrolysis of this compound affords the corresponding diol which under acidic catalysis is transformed into bis-hydroxy ether and 1,4-dioxane derivatives.

Ключевые слова: carvone, lead tetraacetate, gem-acetoxylation reactions, diols, dimers, 1,4-dioxanes.

Язык публикации: английский

DOI: 10.1016/j.mencom.2021.09.034



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