T. P. Trofimova, M. A. Orlova, V. A. Tafeenko, A. N. Proshin, I. S. Glazkova, D. A. Pankratov, “Mono- and binuclear chloride complexes of bismuth(iii) with 2-aminopyrimidine cations depending on specific synthetic route”, Mendeleev Commun., 30:2 (2020), 202

Эта публикация цитируется в 4 статьях

Communications

Mono- and binuclear chloride complexes of bismuth(iii) with 2-aminopyrimidine cations depending on specific synthetic route

T. P. Trofimova^ab, M. A. Orlova^ac, V. A. Tafeenko^a, A. N. Proshin^b, I. S. Glazkova^a, D. A. Pankratov^a

^a Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^b Institute of Physiologically Active Compounds, Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
^c N.I. Pirogov Russian National Research Medical University, Moscow, Russian Federation

Аннотация: Complexes of Biⁱⁱⁱ with 2-aminopyrimidine cations with metal-to-ligand ratios of 1:3 or 2:4 (depending on reaction conditions) were synthesized and characterized by elemental analysis, ¹H NMR spectroscopy, and single crystal X-ray crystallography. The possibility of conversion of the latter complex into the former one was demonstrated. The determined cytotoxicity depended on the structure of these complexes.

Ключевые слова: 2-aminopyrimidine, bismuth(iii) complexes, X-ray crystallography, XRD-method, MTT-assay.

Язык публикации: английский

DOI: 10.1016/j.mencom.2020.03.024

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