D. S. Yambulatov, P. A. Petrov, Yu. V. Nelyubina, A. A. Starikova, A. A. Pavlov, D. Y. Aleshin, S. A. Nikolaevskii, M. A. Kiskin, M. N. Sokolov, I. L. Eremenko, “Rare example of structurally characterized mononuclear N-heterocyclic carbene containing zinc carboxylate”, Mendeleev Commun., 30:3 (2020), 293

Эта публикация цитируется в 12 статьях

Communications

Rare example of structurally characterized mononuclear N-heterocyclic carbene containing zinc carboxylate

D. S. Yambulatov^a, P. A. Petrov^bc, Yu. V. Nelyubina^ad, A. A. Starikova^e, A. A. Pavlov^d, D. Y. Aleshin^d, S. A. Nikolaevskii^a, M. A. Kiskin^a, M. N. Sokolov^bc, I. L. Eremenko^ad

^a N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b A.V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
^c Novosibirsk State University, Novosibirsk, Russian Federation
^d A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
^e Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russian Federation

Аннотация: An adduct of Zn^II pivalate with N-heterocyclic carbene 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene has been prepared and characterized by X-ray diffraction analysis, NMR spectroscopy and DFT calculations. The compound preserves mononuclear structure in solution and does not switch the coordination mode from normal to abnormal.

Ключевые слова: N-heterocyclic carbenes, carboxylate complexes, zinc(II), DFT calculations, X-ray crystallography.

Язык публикации: английский

DOI: 10.1016/j.mencom.2020.05.010

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