D. A. Rusanov, A. B. Myshlyavtsev, E. A. Silyanova, A. V. Samet, V. V. Semenov, “Pseudonitrosites as masked nitroalkenes in the Barton–Zard pyrrole synthesis”, Mendeleev Commun., 30:4 (2020), 485

Эта публикация цитируется в 2 статьях

Communications

Pseudonitrosites as masked nitroalkenes in the Barton–Zard pyrrole synthesis

D. A. Rusanov^ab, A. B. Myshlyavtsev^ab, E. A. Silyanova^a, A. V. Samet^a, V. V. Semenov^a

^a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b D.Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation

Аннотация: 3-Aryl-4-methylpyrrole-2-carboxylates were prepared via the Barton–Zard reaction using pseudonitrosites as a source of the corresponding nitroalkenes. The starting pseudonitrosites were, in turn, obtained via addition of N₂O₃ to propenylbenzenes available from the natural plant essential oils.

Ключевые слова: Barton–Zard reaction, pseudonitrosites, propenylbenzenes, isomerization, pyrroles, lamellarins.

Язык публикации: английский

DOI: 10.1016/j.mencom.2020.07.026

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