E. D. Mordvinova, O. A. Snytnikova, V. A. Salomatova, V. V. Yanshole, V. P. Grivin, I. P. Pozdnyakov, “Direct UVC photodegradation of imipramine in aqueous solutions: a mechanistic study”, Mendeleev Commun., 30:5 (2020), 654

Эта публикация цитируется в 2 статьях

Communications

Direct UVC photodegradation of imipramine in aqueous solutions: a mechanistic study

E. D. Mordvinova^ab, O. A. Snytnikova^bc, V. A. Salomatova^ab, V. V. Yanshole^bc, V. P. Grivin^ab, I. P. Pozdnyakov^ab

^a V.V. Voevodsky Institute of Chemical Kinetics and Combustion, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
^b Novosibirsk State University, Novosibirsk, Russian Federation
^c International Tomography Center, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation

Аннотация: Mechanism of direct UVC photolysis of dibenzazepine-type drug imipramine (IMI) was revealed by the combination of laser flash photolysis for the detection of short lived intermediates and steady-state photolysis coupled with LC-MS for identification of final products. Both quantum yield of IMI photoionization and molar absorption coefficient of IMI radical cation were determined for the first time.

Ключевые слова: pharmaceuticals, dibenzazepines, antidepressants, UVC photolysis, laser flash photolysis, photodegradation, radicals, photoionization, water treatment.

Язык публикации: английский

DOI: 10.1016/j.mencom.2020.09.034

	*Дополнительные материалы:*
		Supplementary_data_1.pdf	143.7 Kb