L. Yu. Ukhin, L. G. Kuz'mina, D. V. Alexeenko, L. V. Belousova, A. S. Morkovnik, G. S. Borodkin, T. N. Gribanova, “Uncommon condensations of 1,2,3-triketone 2-oximes with o-phenylenediamine”, Mendeleev Commun., 29:1 (2019), 111

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Communications

Uncommon condensations of 1,2,3-triketone 2-oximes with o-phenylenediamine

L. Yu. Ukhin^a, L. G. Kuz'mina^b, D. V. Alexeenko^a, L. V. Belousova^a, A. S. Morkovnik^a, G. S. Borodkin^a, T. N. Gribanova^a

^a Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russian Federation
^b N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Аннотация: A condensation of 2-hydroxyimino-5,5-dimethylcyclohexane-1,3-dione, ninhydrin oxime and 3-hydroxyiminopentane-2,4-dione with o-phenylenediamine in the presence of CF₃COOH provided 6,6-dimethyl-6,7-dihydroquinoxalino-[2,3-a]phenazine, benzimidazo[2′,1′:1,2]isoquino[3,4-b]quinoxaline, and 2-acetyl-3-methylquinoxaline oxime, respectively. An ability to form stacking dimers was found for the second product.

Язык публикации: английский

DOI: 10.1016/j.mencom.2019.01.038

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