O. A. Kraevaya, A. V. Chernyak, A. F. Shestakov, P. A. Troshin, “Displacement of methoxy groups by thiol residues on the fullerene cage”, Mendeleev Commun., 34:3 (2024), 411

Communications

Displacement of methoxy groups by thiol residues on the fullerene cage

O. A. Kraevaya^a, A. V. Chernyak^ab, A. F. Shestakov^ac, P. A. Troshin^ad

^a Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
^b Yu.A. Osipyan Institute of Solid State Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
^c Department of Fundamental Physical and Chemical Engineering, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^d Zhengzhou Research Institute, Harbin Institute of Technology, Zhengzhou, China

Аннотация: Methoxy groups on the fullerene cage in compound C₆₀(OMe)₅Br were displaced by thiol residues of methyl 3-mercaptopropanoate thus leading to C₆₀(SCH₂CH₂CO₂Me)₅H product. The structure of the product was established by NMR spectroscopy.

Ключевые слова: alkoxy fullerene derivative, thiols, alcohols, substitution, sulfides, cyclopentadienyl-type addition pattern.

Язык публикации: английский

DOI: 10.1016/j.mencom.2024.04.032

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