M. A. Kosarev, D. E. Gavrilov, I. E. Nifant'ev, A. V. Shlyakhtin, A. N. Tavtorkin, V. P. Dyadchenko, V. A. Roznyatovsky, P. V. Ivchenko, “Ultrafast hydrolytic degradation of 2,3-dihydroxypropyl functionalized poly(ethylene phosphates)”, Mendeleev Commun., 29:5 (2019), 509

Эта публикация цитируется в 7 статьях

Communications

Ultrafast hydrolytic degradation of 2,3-dihydroxypropyl functionalized poly(ethylene phosphates)

M. A. Kosarev^a, D. E. Gavrilov^a, I. E. Nifant'ev^ab, A. V. Shlyakhtin^a, A. N. Tavtorkin^ab, V. P. Dyadchenko^a, V. A. Roznyatovsky^a, P. V. Ivchenko^ab

^a Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^b A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russian Federation

Аннотация: 2,3-Dihydroxypropyl functionalized polyphosphates obtained via controlled acid-catalyzed hydrolysis of 2-[(2,2-dimethyl-1,3-dioxolan-4-yl)methoxy]- or 2-(oxiran-2-ylmethoxy)-1,3,2-dioxaphospholane 2-oxide homopolymers are highly sensitive to basic hydrolysis along the polyphosphate chain.

Язык публикации: английский

DOI: 10.1016/j.mencom.2019.09.010

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