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ЖУРНАЛЫ // Mendeleev Communications // Архив

Mendeleev Commun., 2018, том 28, выпуск 5, страницы 464–466 (Mi mendc1801)

Эта публикация цитируется в 1 статье

Communications

Nickel-coordinated chiral enols and Michael addition intermediate stabilized by the Ni–C bond

L. A. Hayriyana, A. F. Mkrtchyana, M. A. Moskalenkob, V. I. Maleevb, Z. T. Gugkaevab, M. M. Ilyinb, K. K. Babievskyb, P. V. Dorovatovskiic, V. N. Khrustalevcd, A. S. Peregudovb, Yu. N. Belokonb

a Scientific and Production Center ‘Armbiotechnology’ of National Academy of Sciences of Republic Armenia, Yerevan, Armenia
b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
c National Research Centre 'Kurchatov Institute', Moscow, Russian Federation
d Peoples Friendship University of Russia (RUDN University), Moscow, Russian Federation


Аннотация: A representative within a new class of chiral enol NiII complexes derived from a Schiff base of aminoacetone and (S)-2-N-(N-benzylprolinoylamino)benzophenone was prepared, and its performance in nucleophilic addition was estimated. The complex was inert towards aldehydes and activated C=C bonds but reacted with carboxylic anhydrides and di-tert-butyl acetylenedicarboxylate. An unusual Michael addition intermediate stabilized by the Ni–C bond was discovered in the latter reaction.

Язык публикации: английский

DOI: 10.1016/j.mencom.2018.09.003



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