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ЖУРНАЛЫ // Mendeleev Communications // Архив

Mendeleev Commun., 2018, том 28, выпуск 5, страницы 527–529 (Mi mendc1824)

Эта публикация цитируется в 27 статьях

Communications

Stable O,N-heterocyclic plumbylenes bearing sterically hindered o-amidophenolate ligands

K. V. Tsysa, M. G. Chegerevab, G. K. Fukina, A. V. Piskunova

a G.A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhnii Novgorod, Russian Federation
b Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russian Federation


Аннотация: The reaction of dilithium salts of 4,6-di-tert-butyl-N-(R)-o-aminophenols with PbCl2 leads to the formation of new O,N-heterocyclic plumbylenes [R is But or dipp (2,6-diiso-propylphenyl)]. Both compounds possess dimeric structure in crystals according to the X-ray analysis of a single crystal. The formation of unstable paramagnetic plumbylene was detected during an oxidation of 4,6-di-tert-butyl-N-(tert-butyl)-o-aminophenolatolead(II) with HgBr2.

Язык публикации: английский

DOI: 10.1016/j.mencom.2018.09.026



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