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ЖУРНАЛЫ // Mendeleev Communications // Архив

Mendeleev Commun., 2017, том 27, выпуск 3, страницы 243–245 (Mi mendc1955)

Эта публикация цитируется в 3 статьях

Communications

Spontaneous reaction of malonyl peroxides with methanol

M. A. Lapitskaya, V. A. Vil', L. L. Vasiljeva, E. D. Daeva, A. O. Terent'ev, K. K. Pivnitsky

N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation


Аннотация: The spontaneous reaction of disubstituted malonyl peroxides (MPOs) with methanol affording monopermalonic acid monomethyl esters is fast (minutes) for lower homologues but is sharply decelerated (days) for the higher ones. Spirocyclopropyl-MPO is an exception in which the nucleophilic opening of the spiroactivated cyclopropane ring leads to 2,4-dimethoxy-2-carboxybutanoic acid.

Язык публикации: английский

DOI: 10.1016/j.mencom.2017.05.008



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