V. Yu. Kotov, N. P. Simonenko, A. B. Ilyukhin, “Hybrid halobismuthates: a coordinated BrIBr– anion”, Mendeleev Commun., 27:5 (2017), 454

Эта публикация цитируется в 17 статьях

Communications

Hybrid halobismuthates: a coordinated BrIBr^– anion

V. Yu. Kotov^ab, N. P. Simonenko^a, A. B. Ilyukhin^a

^a N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b Higher Chemical College of the Russian Academy of Sciences, D.I. Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation

Аннотация: A new organic-inorganic hybrid material containing bromobismuthate anions and bis(1-pyridino)hexane cations was synthesized and characterized. The reaction between (C₁₆H₂₂N₂)₂Bi₂Br₁₀ and HBr in the presence of HI vapor afforded (C₁₆H₂₂N₂)₃(BiBr₆)₂ as the main product and (C₁₆H₂₂N₂)₃(BiBr₆)(BiBr₇I) as a by-product containing the BrIBr^– anion coordinated by bismuth.

Язык публикации: английский

DOI: 10.1016/j.mencom.2017.09.007

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