M. G. Medvedev, F. N. Novikov, I. S. Bushmarinov, A. A. Zeifman, M. S. Polkovnichenko, O. V. Stroganov, G. G. Chilov, K. A. Lyssenko, I. Svitanko, “Charge redistribution in the SpnF-catalyzed Diels–Alder reaction”, Mendeleev Commun., 27:5 (2017), 500

Communications

Charge redistribution in the SpnF-catalyzed Diels–Alder reaction

M. G. Medvedev^ab, F. N. Novikov^a, I. S. Bushmarinov^b, A. A. Zeifman^a, M. S. Polkovnichenko^c, O. V. Stroganov^a, G. G. Chilov^a, K. A. Lyssenko^b, I. Svitanko^a

^a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
^c Moscow State High School No. 192, Moscow, Russian Federation

Аннотация: Investigation of charge delocalization (redistribution) in a SpnF-catalyzed reaction that proceeds through overlapping Diels–Alder and bis-pericyclic mechanisms has shown that it is better represented as a nonpolar cycloaddition rather than a cationic rearrangement.

Язык публикации: английский

DOI: 10.1016/j.mencom.2017.09.024