A. A. Krotova, V. Yu. Kotov, “Unusual stability of anionic associates in mixed solvents”, Mendeleev Commun., 26:2 (2016), 154

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Communications

Unusual stability of anionic associates in mixed solvents

A. A. Krotova^a, V. Yu. Kotov^bc

^a Institute of Natural Sciences, Moscow City Teacher’s Training University, Moscow, Russian Federation
^b N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^c Higher Chemical College of the Russian Academy of Sciences, D.I. Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation

Аннотация: The ion associates [Fe(CN)₆]^4–, M⁺, [Cu edta]^2–, which are observed in the UV-VIS spectra of K₄[Fe(CN)₆] + Na₂[Cu edta] solutions as an absorption band at 500 nm, contain alkali metal cations, and they are more stable in water-organic solutions than in aqueous solutions.

Язык публикации: английский

DOI: 10.1016/j.mencom.2016.03.025