V. G. Shtamburg, S. V. Shishkina, V. V. Shtamburg, A. V. Mazepa, G. K. Kadorkina, R. G. Kostyanovsky, “1-Alkoxyamino-4-dimethylaminopyridinium salts: synthesis and structure†”, Mendeleev Commun., 26:2 (2016), 169

Communications

1-Alkoxyamino-4-dimethylaminopyridinium salts: synthesis and structure^†

V. G. Shtamburg^a, S. V. Shishkina^b, V. V. Shtamburg^a, A. V. Mazepa^c, G. K. Kadorkina^d, R. G. Kostyanovsky^d

^a Ukrainian State University of Chemical Technology, Dnepropetrovsk, Ukraine
^b STC 'Institute for Single Crystals', National Academy of Sciences of Ukraine, Kharkov, Ukraine
^c A.V. Bogatsky Physico-Chemical Institute, National Academy of Sciences of Ukraine, Odessa, Ukraine
^d N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation

Аннотация: N-Alkoxy-N-chlorocarbamates react with 4-dimethyl-aminopyridine yielding 1-alkoxyamino-4-dimethylamino-pyridinium chlorides, new type of O–N–N⁺ geminal systems. The XRD studies of two representative 1-alkoxyamino-pyridinium chlorides revealed the high pyramidal configuration of the central nitrogen atom in O–N–N⁺ geminal system.

Язык публикации: английский

DOI: 10.1016/j.mencom.2016.03.030

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