V. K. Brel, A. V. Samet, L. D. Konyushkin, A. I. Stash, V. K. Belsky, V. V. Semenov, “Levoglucosenone-derived precursors for the stereoselective synthesis of methylene-expanded analogues of C-nucleosides”, Mendeleev Commun., 25:1 (2015), 44

Эта публикация цитируется в 11 статьях

Communications

Levoglucosenone-derived precursors for the stereoselective synthesis of methylene-expanded analogues of C-nucleosides

V. K. Brel^ab, A. V. Samet^c, L. D. Konyushkin^c, A. I. Stash^d, V. K. Belsky^d, V. V. Semenov^c

^a Institute of Physiologically Active Compounds, Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
^b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
^c N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^d L. Ya. Karpov Institute of Physical Chemistry, Moscow, Russian Federation

Аннотация: Simple chiral precursors for the preparation of methylene-expanded C-nucleosides were developed, using as key steps pyrolysis of cellulose to levoglucosenone followed by hydrogenation and introduction of vinyl and ethynyl fragments to the 2-position.

Язык публикации: английский

DOI: 10.1016/j.mencom.2015.01.016

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