Аннотация:
The cationic complex [Cp*Ru(C5Me4CH2)]+ reacts with Et3N primarily giving the ammonium salt [Cp*Ru(C5Me4CH2NEt3)]+. The prolonged standing of the reaction mixture results in the formation of the ether Cp*Ru(C5Me4CH2OCH2C5Me4)RuCp*. The reaction of [Cp*Ru(C5Me4CH2)]+ with PhNEt2 leads to the electrophilic aromatic substitution product [Cp*Ru(C5Me4CH2C6H4NHEt2)]+.