S. Yu. Bylikin, A. A. Korlyukov, A. G. Shipov, D. E. Arkhipov, N. A. Kalashnikova, V. V. Negrebetsky, Yu. I. Baukov, “Regioselective chelation in the reaction of N-trimethylsilyl-N-acetylglycine N’,N’-dimethylamide with chloro(chloromethyl)dimethylsilane”, Mendeleev Commun., 25:2 (2015), 114

Эта публикация цитируется в 5 статьях

Communications

Regioselective chelation in the reaction of N-trimethylsilyl-N-acetylglycine N’,N’-dimethylamide with chloro(chloromethyl)dimethylsilane

S. Yu. Bylikin^ab, A. A. Korlyukov^ac, A. G. Shipov^a, D. E. Arkhipov^ac, N. A. Kalashnikova^a, V. V. Negrebetsky^a, Yu. I. Baukov^a

^a N.I. Pirogov Russian National Research Medical University, Moscow, Russian Federation
^b The Open University, Walton Hall, Milton Keynes, UK
^c A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Аннотация: Regioselective reaction of N-trimethylsilyl-N-acetylglycine N’,N’-dimethylamide with chloro(chloromethyl)dimethylsilane yields chlorosilane MeC(O)N(CH₂SiMe₂Cl)CH₂C(O)NMe₂ with a five-membered C,O-chelate ring involving the N-acetyl group rather than the six-membered ring involving the N’,N’-dimethylamide fragment. According to X-ray data, the pentacoordinate silicon atom in the product has a TBP environment with the halogen and oxygen atoms in axial positions.

Язык публикации: английский

DOI: 10.1016/j.mencom.2015.03.011

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