A. I. Svitan'ko, S. A. Novikova, T. L. Kulova, A. M. Skundin, A. B. Yaroslavtsev, “An improvement in the ionic conductivity and electrochemical characteristics of LiFePO4 by heterogeneous doping with NASICON-type phosphate”, Mendeleev Commun., 25:3 (2015), 207

Эта публикация цитируется в 6 статьях

Communications

An improvement in the ionic conductivity and electrochemical characteristics of LiFePO₄ by heterogeneous doping with NASICON-type phosphate

A. I. Svitan'ko^a, S. A. Novikova^a, T. L. Kulova^b, A. M. Skundin^b, A. B. Yaroslavtsev^a

^a N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, Russian Federation

Аннотация: Composite materials based on LiFePO₄ with olivine structure and Li_1.3Ti_1.7Fe_0.3(PO₄)₃ with NASICON structure have been synthesized and characterized by the XRD analysis, scanning electron microscopy and impedance spectroscopy. The investigation of electrochemical behavior of obtained composites additionally coated with a thin carbon layer demonstrated that the LiFePO₄-based materials doped by phosphate with the NASICON structure exhibit higher electrochemical capacity in comparison with the initial LiFePO₄.

Язык публикации: английский

DOI: 10.1016/j.mencom.2015.05.016