A. A. Korlyukov, M. A. Eskova, I. M. Tkachenko, Yu. N. Kononevich, O. I. Shchegolikhina, A. M. Muzafarov, “Heteroligand nickel siloxane with 4-vinylbenzyl substituents”, Mendeleev Commun., 25:3 (2015), 226

Эта публикация цитируется в 20 статьях

Communications

Heteroligand nickel siloxane with 4-vinylbenzyl substituents

A. A. Korlyukov^a, M. A. Eskova^a, I. M. Tkachenko^b, Yu. N. Kononevich^a, O. I. Shchegolikhina^a, A. M. Muzafarov^a

^a A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
^b Institute of Macromolecular Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine

Аннотация: A new polyherdal nickel siloxane was synthesized by the hydrolysis of triethoxy(4-vinylbenzyl)silane in the presence of NaOH and the subsequent interaction with [Ni(NH₃)₆]Cl₂. The nickel siloxane has a dimeric structure that consists of two polyhedral sandwiched pentanuclear nickel siloxane units linked by very strong O–H···O bonds into infinite chains in a crystal.

Язык публикации: английский

DOI: 10.1016/j.mencom.2015.05.024