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ЖУРНАЛЫ // Mendeleev Communications // Архив

Mendeleev Commun., 2014, том 24, выпуск 6, страницы 358–359 (Mi mendc2581)

Communications

Protonation of Cp*Fe(η5-C6H7) as a convenient procedure for the preparation of the valuable synthon [Cp*Fe(MeCN)3]+

A. S. Romanov, M. M. Vinogradov, D. V. Muratov, A. R. Kudinov

A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation


Аннотация: The (cyclohexadienyl)iron complex Cp*Fe(η5-C6H7) obtained by a reaction of the cation [Cp*Fe(η6-C6H6)]+ with LiAlH4 reacts with HBF4·Et2O or TfOH in MeCN to afford the acetonitrile cation [Cp*Fe(MeCN)3]+ in a high yield. The structure of complex Cp*Fe(η5-C6H7) was determined by X-ray diffraction analysis.

Язык публикации: английский

DOI: 10.1016/j.mencom.2014.11.016



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