M. I. Pleshchev, M. A. Epishina, V. V. Kachala, V. V. Kuznetsov, A. S. Goloveshkin, I. S. Bushmarinov, N. N. Makhova, “Ionic liquid-promoted stereoselective [3 + 2] cycloaddition of 1-hetaryl-2-nitroethenes to azomethine imines generated in situ”, Mendeleev Commun., 23:4 (2013), 206

Эта публикация цитируется в 10 статьях

Communications

Ionic liquid-promoted stereoselective [3 + 2] cycloaddition of 1-hetaryl-2-nitroethenes to azomethine imines generated in situ

M. I. Pleshchev^a, M. A. Epishina^a, V. V. Kachala^a, V. V. Kuznetsov^a, A. S. Goloveshkin^b, I. S. Bushmarinov^b, N. N. Makhova^a

^a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Аннотация: Ionic liquids facilitate regio- and stereoselective [3 + 2] cycloaddition of 1-hetaryl-2-nitroethenes to azomethine imines generated catalytically from 6-Ar-1,5-diazabicyclo[3.1.0]hexanes in the presence of BF₃ Et₂O. The similar reaction is possible in MeCN only for azomethine imine with Ar = 2,4-(MeO)₂C₆H₃ to give a mixture of two diastereomers.

Язык публикации: английский

DOI: 10.1016/j.mencom.2013.07.009

	*Дополнительные материалы:*
		Supplementary_data_1.pdf	210.3 Kb