A. V. Artem'ev, S. F. Malysheva, B. G. Sukhov, N. A. Belogorlova, Yu. V. Gatilov, V. I. Mamatyuk, N. K. Gusarova, “Unexpected redox reaction of alkali metal diselenophosphinates with elemental iodine”, Mendeleev Commun., 22:1 (2012), 18

Эта публикация цитируется в 12 статьях

Unexpected redox reaction of alkali metal diselenophosphinates with elemental iodine

A. V. Artem'ev^a, S. F. Malysheva^a, B. G. Sukhov^a, N. A. Belogorlova^a, Yu. V. Gatilov^b, V. I. Mamatyuk^b, N. K. Gusarova^a

^a A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russian Federation
^b N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation

Аннотация: Redox reaction between alkali metal diselenophosphinates R2P(Se)SeM (M = Na, K) and elemental iodine in a 2:1 molar ratio (1,4-dioxane, room temperature, 2min) gives bis(diorganylselenophosphoryl)selenides [R₂P(Se)]₂Se and bis(diorganylselenophosphoryl) triselenides [R₂P(Se)]₂Se₃ in 87–90% total yields.

Язык публикации: английский

DOI: 10.1016/j.mencom.2012.01.006

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