E. Yu. Schmidt, I. A. Bidusenko, N. V. Zorina, I. A. Ushakov, A. I. Mikhaleva, L. V. Klyba, B. A. Trofimov, “Consecutive Reactions of Dialkyl Ethynyl Carbinols with Acetylene in Superbase KOH/DMSO Suspension”, Mendeleev Commun., 22:3 (2012), 132

Эта публикация цитируется в 5 статьях

Consecutive Reactions of Dialkyl Ethynyl Carbinols with Acetylene in Superbase KOH/DMSO Suspension

E. Yu. Schmidt, I. A. Bidusenko, N. V. Zorina, I. A. Ushakov, A. I. Mikhaleva, L. V. Klyba, B. A. Trofimov

A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russian Federation

Аннотация: 2-Methylbut-3-yn-2-ol, a tertiary propargylic alcohol, reacts with acetylene under pressure in superbase KOH/DMSO suspension (80°C, 1h) to afford, along with the expected vinyl ether, 2,2,4,4-tetramethyl-5-methylidene-1,3-dioxolane, 2,5-dimethyl-5-(vinyloxy)hex-3-yn-2-ol and (Z)-2-methyl-4-(2-methylbut-3-yn-2-yloxy)but-3-en-2-ol.

Язык публикации: английский

DOI: 10.1016/j.mencom.2012.05.005