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ЖУРНАЛЫ // Mendeleev Communications // Архив

Mendeleev Commun., 2012, том 22, выпуск 4, страницы 189–191 (Mi mendc2785)

Эта публикация цитируется в 3 статьях

[2 + 2] Photodimerization of the acenaphthylene ruthenium complex [(C5Me4CH2OMe)Ru(η6-C12H8)]+

E. E. Karslyan, A. I. Konovalov, A. O. Borissova, P. V. Petrovskii, A. R. Kudinov

A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Аннотация: The [2+2] photodimerization of the complex [(C5Me4CH2OMe)Ru(η6-C12H8)]+ under visible-light irradiation leads to a mixture of the head-to-head heptacyclene products [(μ-η6: η6-C24H16)Ru2(C5Me4CH2OMe)2]2+ (syn- and anti-) with the predominant formation of the syn-isomer; the structures of both isomers were established by X-ray diffraction analysis.

Язык публикации: английский

DOI: 10.1016/j.mencom.2012.06.005



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