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ЖУРНАЛЫ // Mendeleev Communications // Архив

Mendeleev Commun., 2012, том 22, выпуск 6, страницы 320–322 (Mi mendc2835)

Эта публикация цитируется в 4 статьях

Strong Negative Synergism of Ion Pair Extinction Coefficients in Chloroform–Acetone and Methylene Dichloride–Acetone Mixtures

K. P. Birina, D. S. Duninb, M. V. Tolstykhb, V. Yu. Kotovb

a A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, Russian Federation
b Institute of Natural Sciences, Moscow City Teacher’s Training University, Moscow, Russian Federation

Аннотация: The heteroselective preferential solvation of the iodides of N-heterocyclic aromatic cations in acetone–chloroalkane (chloroform and dichloromethane) binary mixtures results in not only a shift in the maxima of outer-sphere charge transfer absorption bands but also a considerable decrease in the molar extinction coefficients of ion pairs.

Язык публикации: английский

DOI: 10.1016/j.mencom.2012.11.014



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