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ЖУРНАЛЫ // Mendeleev Communications // Архив

Mendeleev Commun., 2011, том 21, выпуск 2, страницы 82–83 (Mi mendc2872)

Эта публикация цитируется в 13 статьях

Convenient synthesis of the ruthenium complexes CpRu(diene)X (X=Cl, Br, I) by naphthalene substitution in [CpRu(C10H8)]+

D. S. Perekalin, E. E. Karslyan, A. O. Borissova, A. R. Kudinov

A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Аннотация: The replacement of naphthalene ligand in the ruthenium complex [CpRu(C10H8)]+ by halide anions in the presence of 1,5-cyclooctadiene (cod) or norbornadiene (nbd) gives important synthetic precursors CpRu(cod)X and CpRu(nbd)X (X=Cl, Br, I) in 60–90% yield; the structure of CpRu(nbd)Br was determined by X-ray diffraction.

Язык публикации: английский

DOI: 10.1016/j.mencom.2011.03.007



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