S. A. Torosyan, F. A. Gimalova, R. F. Valeev, M. S. Miftakhov, “Triethylsilyl triflate-promoted skeletal rearrangement of bottrospicatols”, Mendeleev Commun., 21:3 (2011), 140

Triethylsilyl triflate-promoted skeletal rearrangement of bottrospicatols

S. A. Torosyan, F. A. Gimalova, R. F. Valeev, M. S. Miftakhov

Ufa Institute of Chemistry, Ufa Federal Research Centre of the Russian Academy of Sciences, Ufa, Russian Federation

Аннотация: Treatment of diastereomeric (1R,5R,6R)- and (1R,5R,6S)-6-hydroxymethyl-2,6-dimethyl-7-oxabicyclo[3.2.1]oct-2-enes with Et3SiOTf leads to scalemic (1R,5R,6R)- and (1R,5R,6S)-6-hydroxy-2,6-dimethyl-8-oxabicyclo[3.3.1]non-2-enes.

Язык публикации: английский

DOI: 10.1016/j.mencom.2011.04.008