A. G. Vendilo, H. Rönkkömäki, M. Hannu-Kuure, M. Lajunen, J. Asikkala, E. A. Chernikova, L. H. Lajunen, T. Tuomi, K. I. Popov, “Thermodynamics of complex formation in ionic liquids: cesium complexes with 18-crown-6”, Mendeleev Commun., 19:4 (2009), 196

Эта публикация цитируется в 4 статьях

Thermodynamics of complex formation in ionic liquids: cesium complexes with 18-crown-6

A. G. Vendilo^a, H. Rönkkömäki^b, M. Hannu-Kuure^c, M. Lajunen^c, J. Asikkala^c, E. A. Chernikova^d, L. H. Lajunen^c, T. Tuomi^e, K. I. Popov^f

^a State Research Institute of Chemical Reagents and Highly Pure Chemical Substances, Moscow, Russian Federation
^b Finnish Institute of Occupational Health, Chemical Agents Team, Oulu, Finland
^c Department of Chemistry, University of Oulu, Finland
^d N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^e Finnish Institute of Occupational Health, Chemical Agents Team, Helsinki, Finland
^f Department of Physical and Colloid Chemistry, Moscow State University of Food Technologies, Moscow, Russia

Аннотация: Thermodynamic data for the formation of cesium complexes with 18-crown-6 (18C6, L) [Cs(18C6)]⁺ in N-butyl-4-methyl- pyridinium tetrafluoroborate, 1-butyl-3-methylimidazolium tetrafluoroborate and 1-butyl-3-methylimidazolium dicyanamide, measured using ¹³³Cs NMR spectroscopy at 23–50 ̊C, revealed that the stability of cesium complex in ionic liquids is affected by the nature of both cation and anion of room temperature ionic liquid and is in the range between the values found for water and DMF.

Язык публикации: английский

DOI: 10.1016/j.mencom.2009.07.007