Mendeleev Commun.,
2009 , том 19, выпуск 5, страницы 268–269
(Mi mendc3194)
Эта публикация цитируется в
5 статьях
A ‘magic bridge’: effect of methylene chain length on the photochemistry of radical cations produced from bifunctional X–(CH2 )n –Y molecules
K. B. Nuzhdin a ,
A. V. Kobzarenko a ,
I. I. Barabanov b ,
V. I. Feldman ac a Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
b V.V. Voevodsky Institute of Chemical Kinetics and Combustion, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
c N.S. Enikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences, Moscow, Russian Federation
Аннотация:
The radical cations of aminoamides Me
2 N(CH
2 )
n C(O)NMe
2 and aminoethers Me
2 N(CH
2 )
n OMe reveal selective photoinduced intramolecular H transfer from methylene bridge at a specific chain length (
n = 3).
Ключевые слова:
radical cations, EPR, bifunctional compounds.
Язык публикации: английский
DOI:
10.1016/j.mencom.2009.09.012
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