Incorporation of gas molecules into the frameworks of clathrate hydrates of ion-exchange resins in tetraalkylammonium form

The decomposition temperatures of the hydrates of carboxylic cationites in tetraisoamylammonium (TiAA) and tetrabutylammonium (TBA) forms increase considerably in the presence of hydrogen (at 50MPa, ΔT≈6.5°C for TiAA and 5.0°C for TBA; at 150MPa, ΔT≈8.1°C for TiAA and 6.2°C for TBA).