B. A. Trofimov, E. Yu. Schmidt, A. I. Mikhaleva, N. V. Zorina, I. A. Ushakov, A. V. Afonin, A. M. Vasil'tsov, “Unexpected formation of 4-methyl-1-vinyl-δ-carboline in the reaction of 3-acetylindole oxime with acetylene”, Mendeleev Commun., 17:1 (2007), 40

Эта публикация цитируется в 9 статьях

Unexpected formation of 4-methyl-1-vinyl-δ-carboline in the reaction of 3-acetylindole oxime with acetylene

B. A. Trofimov, E. Yu. Schmidt, A. I. Mikhaleva, N. V. Zorina, I. A. Ushakov, A. V. Afonin, A. M. Vasil'tsov

A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russian Federation

Аннотация: 3-Acetylindole oxime reacts with acetylene (KOH/DMSO, 120 °C, 1 h, 20–25 atm) to unexpectedly give 4-methyl-1-vinyl-δ-carboline 2 in 40% yield along with minor product 1-vinyl-3-(1'-vinyl-2'-pyrrolyl)indole 3 (6%).

Язык публикации: английский

DOI: 10.1016/j.mencom.2007.01.016