L. K. Kibardina, M. A. Pudovik, V. A. Alfonsov, O. N. Kataeva, “Synthesis of enantiopure 1,3,4-thiazaphospholes”, Mendeleev Commun., 17:6 (2007), 323

Эта публикация цитируется в 1 статье

Synthesis of enantiopure 1,3,4-thiazaphospholes

L. K. Kibardina, M. A. Pudovik, V. A. Alfonsov, O. N. Kataeva

A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation

Аннотация: Racemic and (R)-(+)-N-trimethylsilyl-(1-phenyl)ethylamines stereoselectively react with O-phenylchloromethylisothiocyanatothiophosphonate to give a diastereomeric mixture of separable 1,3,4-thiazaphospholes; racemic thiazaphosphole crystallises as a conglomerate.

Ключевые слова: Thiazaphosphole, Racemic and R-(+)-N-trimethylsilyl-(1-phenyl)ethylamines, Cyclization reaction, diastereoselectivity.

Язык публикации: английский

DOI: 10.1016/j.mencom.2007.11.007