A. Ul-Haq, M. Pia Donzello, P. A. Stuzhin, “Iron(II) complexes of hexaphenyl(1,2,5-thia/selenadiazolo)-porphyrazine: the direct replacement of Se by S in the 1,2,5-selenadiazole ring”, Mendeleev Commun., 17:6 (2007), 337

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Iron(II) complexes of hexaphenyl(1,2,5-thia/selenadiazolo)-porphyrazine: the direct replacement of Se by S in the 1,2,5-selenadiazole ring

A. Ul-Haq^a, M. Pia Donzello^b, P. A. Stuzhin^a

^a Department of Organic Chemistry, Ivanovo State University of Chemical Technology, Ivanovo, Russian Federation
^b Dipartimento di Chimica, Universita degli Studi di Roma 'La Sapienza', Roma, Italy

Аннотация: Iron(II) complexes of hexaphenyl(1,2,5-thia/selenadiazolo)porphyrazines have been prepared as bis(pyridine) adducts [Py₂Fe(XN₂)PAPh₆] (X=S, Se) from the corresponding Mg^II complexes obtained by template co-cyclotetramerization of diphenylfumarodinitrile with 1,2,5-thia/selenadiazolo-3,4-dicarbonitriles, and the unusual direct replacement of Se by S in the reaction of [Py₂Fe(SeN₂)PAPh₆] with H₂S has been observed.

Язык публикации: английский

DOI: 10.1016/j.mencom.2007.11.013