I. Yavari, B. Mohtat, H. Zare, “Synthesis of 4,5-dialkyl 5-acetyl-3-oxo-3-(triphenylphosphoranylidene)- tetrahydrofuran-4,5-dicarboxylates”, Mendeleev Commun., 16:2 (2006), 102

Эта публикация цитируется в 5 статьях

Synthesis of 4,5-dialkyl 5-acetyl-3-oxo-3-(triphenylphosphoranylidene)- tetrahydrofuran-4,5-dicarboxylates

I. Yavari^ab, B. Mohtat^b, H. Zare^b

^a Department of Chemistry, Tarbiat Modarres University, Tehran, Iran
^b Department of Chemistry, Science and Research Branch, Islamic Azad Univeristy, Ponak, Tehran, Iran

Аннотация: Alkyl 2-chloroacetoacetates undergo a complex reaction with dialkyl acetylenedicarboxylates in the presence of triphenylphosphine to produce a nearly 1:1 mixture of the cis/trans isomers of dialkyl 5-acetyl-2-oxo-3-(triphenylphosphoranylidene)tetrahydrofuran- 4,5-dicarboxylates in excellent yields.

Язык публикации: английский

DOI: 10.1070/MC2006v016n02ABEH002281