Synthesis and structure of the binuclear and mononuclear complexes Co2(μ-OH2)2(μ-OOCBut)2(Hdmpz)4[OS(O)2CF3]2•2THF and Co(Hdmpz)2(MeCN)2(OH2)2[OS(O)2CF3]2·THF (Hdmpz = 3,5-dimethylpyrazole)
Аннотация:
The reaction of Co2(μ-OOCBut)2(Hdmpz)4(MeCN)2[OS(O)2CF3]2 (Hdmpz = 3,5-dimethylpyrazole) with water in THF at room temperature gave the binuclear and mononuclear complexes Co2(μ-OH2)2(μ-OOCBut)2(Hdmpz)4[OS(O)2CF3]2•2THF and Co(Hdmpz)2(MeCN)2(OH2)2[OS(O)2CF3]2·THF, which were characterised using X-ray diffraction analysis.
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