Prospects for the determination of thermodynamic and kinetic parameters of electrode reaction intermediates by laser photoemission

The method of voltammetric time-resolved waves (TRW) based on a comparative analysis of experimental and simulated curves of photoemissionally generated intermediates was used to determine the thermodynamic and kinetic properties of the R/R⁻ redox pairs for the benzyl PhCH2⋅ and benzhydryl Ph2CH⋅ radicals.