Electrochemistry of 1,1,2,2,3,3-hexa(2,6-diethylphenyl)cyclotristannane. The first examples of electrochemical generation of a stannylene radical anion and a tristannane radical cation
Аннотация:
The radical anion of di(2,6-diethylphenyl)stannylene (Ar2Sn) has been generated by the electrochemical reduction of cyclotristannane cyclo-(Ar2Sn)3, and the electrochemical oxidation of cyclo-(Ar2Sn)3 resulted in Sn–Sn bond cleavage with the formation of the radical cation of tristannane.