V. P. Shevchenko, I. Yu. Nagaev, N. F. Myasoedov, A. B. Tuzikov, N. V. Bovin, “Palladium-catalysed 3H-labelling of Neu5AcOMe and spacered 3′-sialyllactose”, Mendeleev Commun., 12:6 (2002), 215

Palladium-catalysed ³H-labelling of Neu5AcOMe and spacered 3′-sialyllactose

V. P. Shevchenko^a, I. Yu. Nagaev^a, N. F. Myasoedov^a, A. B. Tuzikov^b, N. V. Bovin^b

^a Institute of Molecular Genetics, Russian Academy of Sciences, Moscow, Russian Federation
^b M.M. Shemyakin–Yu.A. Ovchinnikov Institute of Bioorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Аннотация: Randomly ³H-substituted Neu5AcαOMe and Neu5Acα2-3Galβ1-4Glc-NHCOCH₂NH₂ were synthesised from ‘cold’ components using catalytic solid-phase exchange under the following conditions: tritium gas, Pd/CaCO₃, 140–160 °C.

Язык публикации: английский

DOI: 10.1070/MC2002v012n06ABEH001654