Аннотация:
Previously unknown 1,3,5,8-tetramethyl-6,7-di[2′-(closo-monocarbon carborane-1″-yl caesium)methoxycarbonylethyl]porphyrin and 1,3,5,8-tetramethyl-2,4-divinyl-6,7-di[2′-(closo-monocarbon carborane-1″-yl caesium)methoxycarbonylethyl]porphyrin were synthesised in the reactions of deuteroporphyrin IX and protoporphyrin IX, respectively, with (1-hydroxymethyl-closo-monocarbon carborane)caesium.