Yu. D. Orlov, V. V. Takhistov, “A new procedure for estimating the enthalpies of formation for RCH2·free radicals”, Mendeleev Commun., 10:1 (2000), 23

A new procedure for estimating the enthalpies of formation for RCH₂·free radicals

Yu. D. Orlov^a, V. V. Takhistov^b

^a Department of Physics and Technology, Tver State University, Tver, Russian Federation
^b St. Petersburg Scientific Centre of Ecological Safety, Russian Academy of Sciences, St. Petersburg, Russian Federation

Аннотация: From the observed regularity that for certain substituents the ΔΔHf0 values for Me• → RCH2• free radicals and CH₂=CH₂ → → RCH=CH₂ molecules are nearly identical, new or corrected values for the enthalpies of formation were estimated for about 30 gaseous free radicals and molecules.

Язык публикации: английский

DOI: 10.1070/MC2000v010n01ABEH001122