R. O. Burlutsky, E. S. Yudina, A. V. Churakov, D. A. Lemenovskii, V. P. Dyadchenko, “Synthesis of new ferrocenyl-containing tertiary alcohols, analogs of l-prolinol-based organocatalysts”, Mendeleev Commun., 34:1 (2024), 64

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Communications

Synthesis of new ferrocenyl-containing tertiary alcohols, analogs of l-prolinol-based organocatalysts

R. O. Burlutsky^a, E. S. Yudina^a, A. V. Churakov^b, D. A. Lemenovskii^a, V. P. Dyadchenko^a

^a Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^b N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Аннотация: Syntheses of new ferrocenyl-containing tertiary alcohols derived from l-proline were developed. In these alcohols,two ferrocenyl groups are bonded at prolinol moiety directly or through p-phenylene spacer. Specific features for the ferrocene Grignard reagents were discovered.

Ключевые слова: asymmetric organocatalysis, ferrocene, proline, tert-butoxycarbonyl protective group, ferrocenylmagnesium bromide, chiral tertiary alcohols, X-ray molecular structure.

Язык публикации: английский

DOI: 10.1016/j.mencom.2024.01.019

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