L. Ya. Zakharova, F. G. Valeeva, L. A. Kudryavtseva, A. I. Konovalov, “The kinetics of solvolysis of p-nitrophenyl bis(chloromethyl)phosphinate in a micellar solution of sodium dodecyl sulfate in ethylene glycol: catalysis by metal ions”, Mendeleev Commun., 10:6 (2000), 241

Эта публикация цитируется в 3 статьях

The kinetics of solvolysis of p-nitrophenyl bis(chloromethyl)phosphinate in a micellar solution of sodium dodecyl sulfate in ethylene glycol: catalysis by metal ions

L. Ya. Zakharova^a, F. G. Valeeva^a, L. A. Kudryavtseva^a, A. I. Konovalov^b

^a A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation
^b Alexander Butlerov Institute of Chemistry, Kazan Federal University, Kazan, Russian Federation

Аннотация: A 30-fold acceleration of the title reaction due to an increase in the activation entropy and activation enthalpy in the micellar pseudophase compared to ethylene glycol was found; Mg²⁺, Zn²⁺ and La³⁺ ions accelerate the solvolysis by factors of 5, 8 and 20, respectively.

Язык публикации: английский

DOI: 10.1070/MC2000v010n06ABEH001337