G. A. Dushenko, I. E. Mikhailov, A. Zschunke, G. Reck, B. Schulz, C. Muegge, V. I. Minkin, “Synthesis and structure of stable chiral AuI complexes with N,N′-diaryl-α-naphthamidinium-N′-[2,3,4,5-tetra(methoxycarbonyl)cyclopentadien-1-yl] ylides”, Mendeleev Commun., 9:2 (1999), 67

Эта публикация цитируется в 8 статьях

Synthesis and structure of stable chiral Au^I complexes with N,N′-diaryl-α-naphthamidinium-N′-[2,3,4,5-tetra(methoxycarbonyl)cyclopentadien-1-yl] ylides

G. A. Dushenko^a, I. E. Mikhailov^a, A. Zschunke^b, G. Reck^b, B. Schulz^b, C. Muegge^c, V. I. Minkin^a

^a Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russian Federation
^b Federal Institute for Materials Research and Testing, Berlin, Germany
^c Department of Chemistry, Humboldt University, Berlin, Germany

Аннотация: Novel N-amidine-functionalized cyclopentadiene gold(I) complexes [C₅(CO₂Me)₄{ArNC(α-C₁₀H₇)NAr}]Au(PPh₃) have been prepared, and their stable chiral structure with the Au–N bond [2.091(6) Å] and the additional coordination Au···π-system of the cyclopentadiene ring has been proved by X-ray crystallography and NMR spectroscopy.

Язык публикации: английский

DOI: 10.1070/MC1999v009n02ABEH001064