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Полная версия
ЖУРНАЛЫ // Mendeleev Communications // Архив
Mendeleev Commun., 1999, том 9, выпуск 5, страницы 211–212 (Mi mendc4602)
Эта публикация цитируется в 6 статьях

A Mössbauer study of pentavalent iron in a vanadium(V) oxide matrix

S. K. Dedushenkoa, Yu. D. Perfil'evb, D. Chebukovbc, D. A. Pankratovb, Yu. M. Kiselevb

a N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
b Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
c N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Аннотация: The formation of iron in the 5+ oxidation state was observed in iron-doped vanadium(V) oxide; this state is characterised by a singlet with the isomer shift δ = –0.56±0.01 mm s–1 relative to α-iron in the Mössbauer spectrum at room temperature.

Язык публикации: английский

DOI: 10.1070/MC1999v009n05ABEH001157


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